Lampung Natural Zeolite as a Green Solution: Heavy Metal Waste Treatment through Flotation-Filtration Method

  • Asep Setiawan University of Indonesia
Keywords: COD Reduction, Flotation–Filtration, Heavy Metal Removal, Iron (Fe) Wastewater, Zeolite Adsorption

Abstract

Purpose of the study: This study aims to evaluate and compare the effectiveness of flotation, filtration, and combined flotation–filtration processes in removing iron (Fe) and reducing Chemical Oxygen Demand (COD) from synthetic wastewater.

Methodology: This study employed flotation, filtration, and combined flotation–filtration methods using a ceramic membrane filtration unit, vacuum pump, air–ozone generator, and synthetic wastewater containing Fe, zeolite, Sodium Lauryl Sulfate (SLS), and Poly-Aluminum Chloride (PAC). Data were analyzed using concentration measurement and percentage removal efficiency calculations.

Main Findings: The combined flotation–filtration process showed the highest performance, achieving Fe removal efficiency of 94.74% with final concentration of 5.26 mg/L. Filtration and flotation showed lower efficiencies. COD reduction was more stable in filtration but more effective initially in flotation–filtration. Membrane fouling was lower in flotation–filtration, resulting in higher permeate volume compared to filtration alone.

Novelty/Originality of this study: This study presents a simultaneous flotation–filtration system integrated with air–ozone injection to enhance pollutant removal and reduce membrane fouling. It highlights the dual role of air–ozone as an oxidizing and cleaning agent, offering improved efficiency and membrane durability compared to conventional single-process methods.

References

T. E. Oladimeji, M. Oyedemi, M. E. Emetere, O. Agboola, J. B. Adeoye, and O. A. Odunlami, “Review on the impact of heavy metals from industrial wastewater effluent and removal technologies,” Heliyon, vol. 10, no. e40370, pp. 1–30, 2024, doi: 10.1016/j.heliyon.2024.e40370.

K. H. Hama Aziz, F. S. Mustafa, K. M. Omer, S. Hama, R. F. Hamarawf, and K. O. Rahman, “Heavy metal pollution in the aquatic environment: efficient and low-cost removal approaches to eliminate their toxicity: a review,” RSC Adv., vol. 13, no. 26, pp. 17595–17610, 2023, doi: 10.1039/d3ra00723e.

X. Huang, X. Shi, and H. Zeng, “How far does the Copper/Nickle recovery from the practical application in the electroplating wastewater?,” Resour. Conserv. Recycl. Adv., vol. 19, no. 200170, pp. 1–7, 2023, doi: 10.1016/j.rcradv.2023.200170.

B. C. Gonçalves et al., “Technologies for the recovery of nickel and copper from electroplating industrial effluent,” in Metal Value Recovery from Industrial Waste Using Advanced Physicochemical Treatment Technologies, Elsevier, 2025, pp. 167–195. doi: 10.1016/B978-0-443-21884-2.00010-1.

W. Jadaa and H. Mohammed, “Heavy metals – definition, natural and anthropogenic sources of releasing into ecosystems, toxicity, and removal methods – An overview tudy,” J. Ecol. Eng., vol. 24, no. 6, pp. 249–271, 2023, doi: 10.12911/22998993/162955.

Renuka and D. Patyal, “Bioaccumulation and Biomagnification: The Cascading Effects of Toxic Metals in the Biosphere,” in Global Perspectives of Toxic Metals in Bio Environs, Cham: Springer Nature Switzerland, 2025, pp. 369–394. doi: 10.1007/978-3-031-89725-2_14.

Y. G. Ko, “Hybrid method integrating adsorption and chemical precipitation of heavy metal ions on polymeric fiber surfaces for highly efficient water purification,” Chemosphere, vol. 363, pp. 1–27, Sep. 2024, doi: 10.1016/j.chemosphere.2024.142909.

C. N. Onyenanu and J. T. Nwabanne, “A critical review of ion lotation as a sustainable wastewater treatment technique: Scope, efficiency, and application,” Int. J. Appl. Nat. Sci., vol. 3, no. 2, pp. 98–110, 2025, doi: 10.61424/ijans.v3i2.344.

M. Bilal et al., “The challenges and prospects of recovering fine copper sulfides from tailings using different flotation techniques: A review,” Minerals, vol. 12, no. 5, pp. 1–20, 2022, doi: 10.3390/min12050586.

A. Yang and L. Wang, “A fundamental study of flotation separation of mineral particles using ultrasound-induced bubbles,” Miner. Eng., vol. 207, no. 108573, pp. 1–13, 2024, doi: 10.1016/j.mineng.2024.108573.

M. Mirhaj, S. Labbaf, M. Tavakoli, and A. M. Seifalian, “Emerging treatment strategies in wound care,” Int. Wound J., vol. 19, no. 7, pp. 1934–1954, 2022, doi: 10.1111/iwj.13786.

L. H. Butterfield and Y. G. Najjar, “Immunotherapy combination approaches: mechanisms, biomarkers and clinical observations,” Nat. Rev. Immunol., vol. 24, no. 6, pp. 399–416, Jun. 2024, doi: 10.1038/s41577-023-00973-8.

G. A. Oliveira, Ê. L. Machado, R. S. Knoll, N. Dell’Osbel, G. S. Colares, and L. R. Rodrigues, “Combined system for wastewater treatment: ozonization and coagulation via tannin-based agent for harvesting microalgae by dissolved air flotation,” Environ. Technol., vol. 43, no. 9, pp. 1370–1380, Apr. 2022, doi: 10.1080/09593330.2020.1830181.

A. D. M. de Medeiros, C. J. G. da Silva Junior, J. D. P. de Amorim, I. J. B. Durval, A. F. de Santana Costa, and L. A. Sarubbo, “Oily wastewater treatment: Methods, challenges, and trends,” Processes, vol. 10, no. 4, pp. 1–20, 2022, doi: 10.3390/pr10040743.

K. Asgari, H. Khoshdast, F. Nakhaei, M. R. Garmsiri, Q. Huang, and A. Hassanzadeh, “A Review on floc-flotation of fine particles: Technological aspects, mechanisms, and future perspectives,” Miner. Process. Extr. Metall. Rev., vol. 45, no. 7, pp. 669–696, Oct. 2024, doi: 10.1080/08827508.2023.2236770.

R. S. Rusidi et al., “Microplastics pollution mitigation in wastewater treatment: Current practices, challenges, and future perspectives,” Malaysian J. Anal. Sci., vol. 28, no. 1, pp. 79–96, 2024.

M. Li et al., “Current trends in the detection and removal of heavy metal ions using functional materials,” Chem. Soc. Rev., vol. 52, no. 17, pp. 5827–5860, 2023, doi: 10.1039/d2cs00683a.

J. Ayach et al., “Comparing conventional and advanced approaches for heavy metal removal in wastewater treatment: An in-depth review emphasizing filter-based strategies,” Polymers (Basel)., vol. 16, no. 14, pp. 1–25, 2024, doi: 10.3390/polym16141959.

I. Rodríguez-Iznaga, M. G. Shelyapina, and V. Petranovskii, “Ion exchange in natural clinoptilolite: Aspects related to its structure and applications,” Minerals, vol. 12, no. 12, pp. 1–38, 2022, doi: 10.3390/min12121628.

N. Kordala and M. Wyszkowski, “Zeolite properties, methods of synthesis, and selected applications,” Molecules, vol. 29, no. 5, pp. 1–25, 2024, doi: 10.3390/molecules29051069.

A. Sanjaya et al., “Alkaline activated natural zeolite as a microbial immobilization media in anaerobic digestion for tapioca wastewater treatment,” J. Teknol. Lingkung., vol. 26, no. 2, pp. 173–182, 2025, doi: 10.55981/jtl.2025.7432.

S. Aulia, W. Simanjuntak, K. D. Pandiangan, and M. Rilyanti, “Transformation of lampung natural zeolite into zeolite-a by aluminium addition and application as catalyst for biomass pyrolysis,” Indones. J. Energy, vol. 7, no. 2, pp. 124–140, 2024, doi: 10.33116/ije.v7i2.199.

L. F. De Magalhães, G. R. Da Silva, and A. E. C. Peres, “Zeolite application in wastewater treatment,” Adsorpt. Sci. Technol., vol. 2022, pp. 1–26, 2022, doi: 10.1155/2022/4544104.

M. Senila and O. Cadar, “Modification of natural zeolites and their applications for heavy metal removal from polluted environments: Challenges, recent advances, and perspectives,” Heliyon, vol. 10, no. 3, pp. 1–17, 2024, doi: 10.1016/j.heliyon.2024.e25303.

R. O. A. Rahman, A. M. El-Kamash, and Y. T. Hung, “Aplicaciones de la nanozeolita en el tratamiento de aguas residuales:Una descripción general,” Water (Switzerland), vol. 14, no. 2, pp. 1–30, 2022.

T. Rad, I. Așchilean, O. Gavriș, and R. A. Felseghi, “Sludge from sewage treatment plants and zeolite: A Bibliometric and SWOT-based review,” Water (Switzerland), vol. 18, no. 5, pp. 1–20, 2026, doi: 10.3390/w18050589.

M. L. Katche, A. B. Makokha, S. O. Zachary, and M. S. Adaramola, “A comprehensive review of maximum power point tracking (MPPT) techniques used in solar PV systems,” Energies, vol. 16, no. 5, pp. 1–23, 2023, doi: 10.3390/en16052206.

M. W. Rasheed et al., “Soil moisture measuring techniques and factors affecting the moisture dynamics: A comprehensive review,” Sustain., vol. 14, no. 18, pp. 1–23, 2022, doi: 10.3390/su141811538.

A. Intang, P. Susmanto, M. D. Bustan, and S. Haryati, “Determination of swelling operation parameters to improve the hierarchy of natural zeolite Lampung after synthesis,” South African J. Chem. Eng., vol. 50, no. July, pp. 125–134, 2024, doi: 10.1016/j.sajce.2024.08.004.

A. Askar et al., “Investigation of the efficiency of the ozonator in the process of water purification based on the corona discharge,” J. Ecol. Eng., vol. 24, no. 2, pp. 140–151, 2023, doi: 10.12911/22998993/156610.

G. Sydykova, S. Umbetova, Z. Baimakhanova, G. Abieva, and G. Kurmanbayev, “Modern applications of ozone technology,” Evergreen, vol. 10, no. 4, pp. 2308–2316, 2023, doi: 10.5109/7160908.

I. Rosyadi, Suyitno, Z. Arifin, and T. Sutardi, “Novel approaches to zeolite deactivation mitigation and regeneration in biomass gasification,” J. Therm. Eng., vol. 11, no. 5, pp. 1552–1584, 2025, doi: 10.14744/thermal.0000993.

R. Li et al., “Floc kinetics in dual-coagulation for the treatment of high-concentration surfactant-kaolin wastewater,” J. Polym. Environ., vol. 32, no. 4, pp. 1706–1716, Apr. 2024, doi: 10.1007/s10924-023-03079-3.

M. P. Rayaroth, G. Boczkaj, O. Aubry, U. K. Aravind, and C. T. Aravindakumar, “Advanced oxidation processes for degradation of water pollutants—ambivalent impact of carbonate species: A review,” Water (Switzerland), vol. 15, no. 8, pp. 1–19, 2023, doi: 10.3390/w15081615.

F. Tanos, A. Razzouk, G. Lesage, M. Cretin, and M. Bechelany, “A comprehensive review on modification of titanium dioxide‐based catalysts in advanced oxidation processes for water treatment,” ChemSusChem, vol. 17, no. 6, pp. 1–35, Mar. 2024, doi: 10.1002/cssc.202301139.

Z. Yan et al., “In-situ air bubble for efficient membrane scaling cleaning with a catalytic nanofiber membrane in membrane distillation,” Desalination, vol. 597, p. 118397, Mar. 2025, doi: 10.1016/j.desal.2024.118397.

B. Li et al., “In-situ utilization of membrane foulants (FeOx+MnOx) for the efficient membrane cleaning,” Water Res., vol. 210, p. 118004, Feb. 2022, doi: 10.1016/j.watres.2021.118004.

X. Xu, J. Luo, R. Fan, Y. Wan, and P. Czermak, “Size-based separation of bioactive molecules by membrane technology: beyond molecular weight,” Trends Chem., vol. 7, no. 11, pp. 690–704, Nov. 2025, doi: 10.1016/j.trechm.2025.09.010.

H. N. Blais, K. Schroën, and J. T. Tobin, “A review of multistage membrane filtration approaches for enhanced efficiency during concentration and fractionation of milk and whey,” Int. J. Dairy Technol., vol. 75, no. 4, pp. 749–760, Nov. 2022, doi: 10.1111/1471-0307.12884.

Suyitno, I. Rosyadi, Z. Arifin, T. Sutardi, Sunaryo, and N. Ilminnafik, “Advanced modification of natural zeolites for optimized biogas, syngas, and hydrogen production and purification,” Cogent Eng., vol. 11, no. 1, pp. 1–27, 2024, doi: 10.1080/23311916.2024.2398912.

S. R. Chia, S. Nomanbhay, K. W. Chew, P. L. Show, J. Milano, and A. H. Shamsuddin, “Indigenous materials as catalyst supports for renewable diesel production in Malaysia,” Energies, vol. 15, no. 8, pp. 1–31, 2022, doi: 10.3390/en15082835.

H. Muvel, M. K. Jindal, P. K. Tewari, and V. Anand, “Minimizing oil pollution: a review of current status and its treatment options,” RSC Sustain., vol. 3, no. 9, pp. 3681–3723, 2025, doi: 10.1039/d5su00403a.

M. Bodzek and P. Bodzek, “Remediation of micro- and nanoplastics by membrane technologies,” Membranes (Basel)., vol. 15, no. 3, pp. 1–34, 2025, doi: 10.3390/membranes15030082.

A. Chatterjee, B. S. Ahmed, E. Hallin, and A. Engman, “Testing of machine learning models with limited samples: an industrial vacuum pumping application,” in Proceedings of the 30th ACM Joint European Software Engineering Conference and Symposium on the Foundations of Software Engineering, New York, NY, USA: ACM, Nov. 2022, pp. 1280–1290. doi: 10.1145/3540250.3558943.

M. Di Virgilio, A. Basso Peressut, V. Arosio, A. Arrigoni, S. Latorrata, and G. Dotelli, “Functional and environmental performances of novel electrolytic membranes for PEM fuel cells: A lab-scale case study,” Clean Technol., vol. 5, no. 1, pp. 74–93, 2023, doi: 10.3390/cleantechnol5010005.

Published
2024-12-31
How to Cite
Setiawan, A. (2024). Lampung Natural Zeolite as a Green Solution: Heavy Metal Waste Treatment through Flotation-Filtration Method. Journal of Chemical Learning Innovation, 1(2), 75-85. https://doi.org/10.37251/jocli.v1i2.2999
Section
Articles